| Competències |
| Type A | Code | Competences Specific |
| CE2 | Conèixer els principis físicoquímics fonamentals que regeixen la Química i les seves relacions amb les diferents àrees de la Química. | |
| CE3 | Conèixer els principals elements i compostos orgànics i inorgànics, així com biomolècules, les seves propietats, les seves rutes sintètiques, la seva caracterització i la seva reactivitat. | |
| Type B | Code | Competences Transversal |
| Type C | Code | Competences Nuclear |
| Resultats d'aprenentage |
| Type A | Code | Learning outcomes |
| CE2 |
Conèixer la Química dels compostos de coordinació i els compostos organometàl·lics: preparació, propietats, reactivitat i aplicacions Saber determinar estructures de compostos inorgànics | |
| CE3 |
Conèixer la Química dels compostos de coordinació i els compostos organometàl·lics: preparació, propietats, reactivitat i aplicacions Saber determinar estructures de compostos inorgànics | |
| Type B | Code | Learning outcomes |
| Type C | Code | Learning outcomes |
| Continguts |
| Topic | Sub-topic |
| 1. Coordination compounds | 1.1. Bonding in coordination compounds 1.1.1. Crystal Field Theory (CFT) applied to all the geometries 1.1.1.1. Limits of the Crystal Field Theory 1.1.2. Molecular Orbitals Theory (MOIT) applied to coordination compounds. 1.1.2.1. Octahedral, tetrahedral and square-squared complexes with sigma bond. 1.1.2.2. Sigma bond. Consequences 1.1.2.3. Differences between CFT and MOT in coordination compounds. 1.2. Characterization of inorganic compounds 1.2.1. Electronic spectroscopy of transition metal complexes 1.2.1.1. Types of electronic transitions. Selection rules. Transitions associated mainly to the ligand, charge transfer, transitions associated with the metallic ion (d-d), transitions associated to other ions of the compound (counter-ion). 1.2.1.2. "d" electron energy terms of a transition metal complex 1.2.1.3. Diagrams of Tanabe-Sugano. 1.2.1.4. Band splitting phenomena 1.2.2. Vibrational spectroscopy (IR and Raman) 1.2.2.1. Fundamentals. 1.2.2.2. Application of group theory to molecular vibrations 1.2.2.3. Other aspects in vibrational spectroscopy: Overtones and combination bands, Fermi resonance, solid state effects 1.3. Stability of coordination compounds. Thermodynamic aspects. Chelate effect. Trans effect. 1.4. Substitution reactions. 1.4.1. Substitution reactions in square planar complexes 1.4.2. Substitution reactions in octahedral complexes. 1.4.2.1. Mechanisms 1.4.2.2. Prediction of the inertia/lability. 1.5. Applications of coordination compounds. Examples. |
| 2. Organometallics | 2.1. Introduction. Interests and applications. 2.2. Study of the types of ligands. Stability of organometallic compounds. 2.3. Preparation of organometallic compounds with metal-carbon sigma bond: direct reaction, metathesis reactions, transmetallation, metallation, oxidative addition and addition 1,2. Application of organometallic compounds with metal-carbon sigma bond in organic synthesis. 2.4. Organometallic compounds with metal-carbon pi bond. Metallic carbonyls: types, properties and structure, bond, preparation and applications. Complexes with pi-donor and pi-acceptor ligands: complexes with alkene and alkyne ligands, pi-allylic complexes. 2.5. Oxidative addition and reductive elimination reactions. Mechanisms 2.6. Insertion and elimination reactions. Insertion 1,1- and 1,2- 2.7. Activation of coordinated ligands. Nucleophilic and electrophilic attack reactions. 3.8. Characterization of inorganic compounds by Nuclear Magnetic Resonance spectroscopy r 2.8.1. Nuclei with spin ½ and quadrupolar nuclei 2.8.2. Spectra of abundant isotopes with spin of ½ 2.8.3. Spectra of low abundance isotopes with spin of ½ 2.8.4. Spectra of quadrupolar nuclei 2.8.5. Important nuclei in inorganic chemistry: 1H, 13C , 31P, Transition metals, Other nuclei: 19F , 29Si 2.8.6. Control of reactions. Exchange reaction, special methods: COSY, HETCOR, DEPT 2.9. Application of organometallic compounds in catalytic processes. Hydrogenation and polymerization reactions. |
| 3. Advanced inorganic solids | 3.1. Bonding and structure in inorganic solids 3.2. Real solids: types of defects 3.3. Relationship between defects and the properties of the solid 3.4. Main methods of preparation and characterization of solids. |
| Planificació |
| Methodologies :: Tests | ||||||||||
| Competences | (*) Class hours |
Hours outside the classroom |
(**) Total hours | |||||||
| Activitats Introductòries |
|
1 | 0 | 1 | ||||||
| Sessió Magistral |
|
61 | 65 | 126 | ||||||
| Resolució de problemes, exercicis |
|
30 | 31 | 61 | ||||||
| Atenció personalitzada |
|
1 | 0 | 1 | ||||||
| Proves objectives de preguntes curtes |
|
2 | 6 | 8 | ||||||
| Proves de desenvolupament |
|
4 | 24 | 28 | ||||||
| (*) On e-learning, hours of virtual attendance of the teacher. (**) The information in the planning table is for guidance only and does not take into account the heterogeneity of the students. | ||||||||||
| Metodologies |
| Description | |
| Activitats Introductòries | |
| Sessió Magistral | |
| Resolució de problemes, exercicis | |
| Atenció personalitzada |
| Atenció personalitzada |
| Description |
|
Temps que cada professor té reservat per atendre i resoldre dubtes als alumnes. A causa de l'emergència sanitària, l'atenció a l'estudiant es podrà realitzar mitjançant reunions en línia, en horaris concertats prèviament per correu electrònic, o mitjançant altres eines virtuals. |
| Avaluació |
| Methodologies | Competences | Description | Weight | ||||
| Resolució de problemes, exercicis |
|
13 % | |||||
| Proves objectives de preguntes curtes |
|
15 % | |||||
| Proves de desenvolupament |
|
35% and 35% |
|||||
| Others | 2% |
| Other comments and second exam session | |||
| Fonts d'informació |
| Bàsica |
West, A. R., Basic Solid State Chemistry, Wiley,
West, A. R, Solid State Chemistry, Wiley,
Lesley Smart, Elaine Moore, Solid state chemistry: an introduction, CRC Press,
Hegedus, L. S., TRANSITION METALS IN THE SYNTHESIS OF COMPLEX ORGANIC MOLECULES, University Science Books, |
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| Complementària | |||||||||
| Recomanacions |
| Subjects that are recommended to be taken simultaneously | ||||
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(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.