Type A
|
Code |
Competences Specific |
|
Common |
|
AC1 |
CE1-Make correct use of modern techniques for characterizing chemical compounds. |
|
AC2 |
CE2-Develop a thorough knowledge of the most advanced applications in synthesis and catalysis. |
|
AC3 |
CE3-Correctly apply the most advanced methodologies in synthesis and catalysis. |
|
AC6 |
CE6-Have a fluent command of the specialized terminology in English related to the fields of synthesis, catalysis and molecular design. |
|
AC8 |
CE8-Design synthesis routes for new products using modern techniques of chemical synthesis, chemical and physical structural characterization, high performance experimentation, data analysis and computational chemistry. |
|
AC9 |
CE9-Develop a thorough knowledge of the modern techniques for discovering and optimizing new synthetic processes and new catalysers. |
Type B
|
Code |
Competences Transversal |
|
Common |
|
BC2 |
CT2-Forming opinions on the basis of the efficient management and use of information |
|
BC7 |
Apply ethical principles and social responsibility as a citizen and a professional. |
Type C
|
Code |
Competences Nuclear |
Objectives |
Competences |
|
AC1 AC2 AC3 AC6 AC8 AC9
|
BC2 BC7
|
|
To the aspects of organometallic chemistry needed for homogenous catalysis such as the transition metal-organic ligand bond types and the reactivity of the organometalic involved in catalytic cycles. |
|
|
|
To understand the following most important processes in homogenous catalysis: hydrogenation, carbonylation, C-C and C-heteroatom bond formation, oxidation, catalyst recovery methods and their importance regarding sustainability. |
|
|
|
To design and prepare the most suitable type of catalyst for each process. |
|
|
|
Topic |
Sub-topic |
1.Properties and applications of organometalic compounds. |
|
2.Organometalic compounds with the M-C sigma bond. |
|
3.Neutral pi-donor and pi-accepter ligands. |
|
4.Oxidation addition and reducing elimination reactions. |
|
5.Insertion and elimination reactions. |
|
6.Concepts of homogenous catalysis. Catalytic cycles. |
|
7.Isomerisation. Synthesis of menthol: the Takasago process. |
|
8.Hydrogenation of C=C, C=N, C=O. |
|
9.C-C bond formation reactions: Allylic substitutions, Heck, Suzuki and related reactions.
|
|
10.Carbonylation reactions: Carbonylation of methanol and methyl acetate. |
|
11.Hydroformylation. Phosphate ligands Applications: Solvents, plastifiers and intermediates.
|
|
12.Metathesis reactions. Different generation catalysts.
|
|
Methodologies :: Tests |
|
Competences |
(*) Class hours |
Hours outside the classroom |
(**) Total hours |
Introductory activities |
|
1 |
0 |
1 |
|
Lecture |
|
28 |
42 |
70 |
Seminars |
|
15 |
15 |
30 |
|
Personal attention |
|
2 |
0 |
2 |
|
Extended-answer tests |
|
2 |
8 |
10 |
|
(*) On e-learning, hours of virtual attendance of the teacher. (**) The information in the planning table is for guidance only and does not take into account the heterogeneity of the students. |
Methodologies
|
Description |
Introductory activities |
To introduce the subject. |
Lecture |
Description of the contents of the subject. |
Seminars |
In-depth work on a particular topic. Further discussion of the lecture content, which is linked to professional skills. |
Personal attention |
Time set aside by the teacher to attend to and resolve any queries from the students |
|
Description |
Time that each professor has to speak to students and solve their doubts. Students can contact either by e-mail or in their offices. In the latter case, appointments have to be made. -Dra. Carmen Claver: carmen.calver@urv.cat -Dr. Marcos Garcia: mgsuero@iciq.es |
|
|
Description |
Weight |
Extended-answer tests |
Written test |
75% |
Others |
Participació |
25% |
|
Other comments and second exam session |
During the exams, any mobil telephone, tablet or other device that has not been expressly authorized for the exam must be switched off and out of view. Any attempt to pass any exam of any subject by fraudulent means (be this physical or electronic) will result in the student being awarded a fail for the exam in question. In addition to this, the gravity of the offence may lead the faculty/school to propose that the student be subjected to disciplinary proceedings, which will be initiated by a resolution from the rector. |
Basic |
P.W.N.M. van Leeuwen, Homogeneus Catalysis, Understanging the Art, Ed. Kluver, 2004, Dordrecht
|
The rest of the basic bibliography will be made available once the course has started. |
Complementary |
|
|
(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation. |
|