IDENTIFYING DATA 2018_19
Subject (*) THERMODYNAMICS AND KINETICS Code 19204111
Study programme
Bachelor's Degree in Biotechnology (2009)
Cycle 1st
Descriptors Credits Type Year Period
4 Compulsory Second 2Q
Language
Català
Department Chemical Engineering
Physical and Inorganic Chemistry
Coordinator
GIAMBERINI , MARTA
E-mail marta.giamberini@urv.cat
maria.pantelidou@urv.cat
maria.besora@urv.cat
Lecturers
GIAMBERINI , MARTA
PANTELIDOU -, MARIA
BESORA BONET, MARIA
Web
General description and relevant information The study of systems in equilibrium, through thermodynamics, and the temporal evolution of matter, through kinetics, give complementary visions of the behavior of chemical or biochemical systems. General contents of chemical and kinetic thermodynamics, necessary for biotechnology.

Competences
Type A Code Competences Specific
 A3 Have a good knowledge of biochemistry, enzyme kinetics and mechanisms, metabolism and its regulation.
 A8 Analyse appropriately data and experimental results from the fields of biotechnology with statistical techniques and be able to interpret it.
Type B Code Competences Transversal
 B2 Solve complex problems effectively in the biotechnology field.
Type C Code Competences Nuclear

Learning outcomes
Type A Code Learning outcomes
 A3 Integrate knowledge of thermodynamics and kinetics into the design of biotechnological processes and obtain data for this design in the laboratory and from the literature.
Be able to interpret the data of temporary evolution of chemical systems and to extract kinetic parameters.
 A8 Knows how to apply the principles of thermodynamics to chemical and biochemical processes and to systems in equilibrium.
Know how to relate the conditions of temperature, pressure and composition to the equilibrium constant.
Integrate knowledge of thermodynamics and kinetics into the design of biotechnological processes and obtain data for this design in the laboratory and from the literature.
Type B Code Learning outcomes
 B2 Collect the information they need so that they can solve problems using data and not subjective opinion, and subjecting the information at their disposal to logical analysis.
Type C Code Learning outcomes

Contents
Topic Sub-topic
Review of thermodynamic concepts
State equations
Thermodynamic relations and functions
Ideal gases
Mass and energy balances.
1st, 2nd and 3rd laws.
Gibbs energy and chemical potential.
Transformations of matter Change and phase balance.
Pure substances.
Multicomponent systems.
Phase diagrams
Solutions Composition, mixing magnitudes, ideal and diluted ideal solutions.
Deviation from ideal behavior
Reminder of concepts of chemical kinetics Reaction rate: rate equation, reaction order, rate constant
Mechanisms of reaction: elementary stage, simple reaction, complex reaction.
Apparent constant, pseudoordre
Analysis of kinetic data
Methods of determining reaction orders.
Method of integration by simple reactions.
Pseudo-order reaction. Apparent constant.
Experimental techniques for the determination of reaction rates.
Influence of temperature on the rate of reactions Arrhenius equation.
Arrhenius Theory. Activated complex and frequency factor. Molecular interpretation.
Kinetic treatment of complex reactions Arrhenius equation.
Arrhenius Theory. Activated complex and frequency factor. Molecular interpretation.
Mechanisms of reaction Complexity of mechanisms.
Approximation of the determining step of a reaction.
Steady state approach.
Examples of known mechanisms.
Catalytic mechanisms. Enzymatic catalysis.

Planning
Methodologies  ::  Tests
  Competences (*) Class hours
Hours outside the classroom
(**) Total hours
Introductory activities
2 0 2
Laboratory practicals
A3
A8
10 6 16
Lecture
A3
A8
22 33.75 55.75
Problem solving, exercises
A3
A8
8 12.8 20.8
Personal attention
3 0 3
 
 
(*) On e-learning, hours of virtual attendance of the teacher.
(**) The information in the planning table is for guidance only and does not take into account the heterogeneity of the students.

Methodologies
Methodologies
  Description
Introductory activities Reminder viewed General Chemistry concepts related to Chemical Thermodynamics and Kinetics.
Laboratory practicals
Work oriented to the application of the concepts acquired during the theoretical classes.
Lecture Presentation and development of the different themes, with support of materials accessible through ‘’Moodle’’.
Problem solving, exercises Problems previously delivered to students are solved in class, which also have a collection of problems solved.
Personal attention

The teachers of the subject can be contacted directly in their respective offices or by appointment by e-mail.

Personalized attention
Description
The teachers of the subject can be contacted directly in their respective offices or by appointment by e-mail.

Assessment
Methodologies Competences Description Weight        
Laboratory practicals
A3
A8
They are evaluated through the report and a question in some of the objective tests, according to calendar. 10
Problem solving, exercises
A3
A8
2 partials, one of contents of Thermodynamics and one of Kinetics. The partial have the same weight. 90
Others  
 
Other comments and second exam session

A cada part cal treure com a mínim un 3,5

La segona convocatòria consistirà en una prova escrita sobre tot el contingut de l'assignatura.

Durant les proves d'avaluació, els telèfons mòbils, tablets i altres aparells que no siguin expressament autoritzats per la prova, han d'estar apagats i fora de la vista. La realització demostrativament fraudulenta d'alguna activitat avaluativa d'alguna assignatura tant en suport material com virtual i electrònic comporta a l'estudiant la nota de suspens d'aquesta activitat avaluativa. Amb independència d'això, davant la gravetat dels fets, el centre pot proposar la iniciació d'un expedient disciplinari, que serà incoat mitjançant resolució del rector o rectora.


Sources of information

Basic I. N. LEVINE, Fisicoquímica, vols I y II,, Mc Graw-Hill,
P.W. ATKINS, J. de PAULA, Physical Chemistry for the Life Sciences, Freeman,
P.W. ATKINS, J. de PAULA, The elements of Physical Chemistry, Freeman,
P.W. ATKINS, Química Física, Omega,
I. N. LEVINE, Problemas de Fisicoquímica, McGraw-Hill.,

Complementary

Recommendations


Subjects that it is recommended to have taken before
CHEMISTRY I/19204009
CHEMISTRY II/19204010
(*)The teaching guide is the document in which the URV publishes the information about all its courses. It is a public document and cannot be modified. Only in exceptional cases can it be revised by the competent agent or duly revised so that it is in line with current legislation.