| Educational guide Faculty of Chemistry |
english |
| Synthesis, Catalysis and Molecular Design (2013) |
 Subjects |
| STRUCTURAL DETERMINATION TECHNIQUES |
| Contents |
| IDENTIFYING DATA | 2018_19 |
| Subject | STRUCTURAL DETERMINATION TECHNIQUES | Code | 13685102 | |||||
| Study programme |
|
Cycle | 2nd | |||||
| Descriptors | Credits | Type | Year | Period | ||||
| 6 | Compulsory | First | AN |
|||||
| Competences | Learning aims | Contents |
| Planning | Methodologies | Personalized attention |
| Assessment | Sources of information | Recommendations |
| Topic | Sub-topic |
| MASS SPECTROMETRY |
|
| 1. Introduction. Definitions. High resolution, low resolution. | |
| 2. Ionization methods. |
2.1.- Electron Ionization. Fundamentals. Mechanisms, fragmentations. 2.2. Chemical ionization. Fundamentals. Examples. 2.3. FAB, SIMS, MALDI. Fundamentals. Examples. 2.4. Atmospheric Pressure Ionization (API) techniques. ESI and APCI: Fundamentals. Description. |
| 3.- Instrumentation |
3.1.- Analyzers: Quadrupole, Magnetic Sector, Ion Trap, Time of flight (TOF), Fourier Transform Ion Ciclotron Resonance (FT-ICR). 3.1.1.- Mass Spectrometry in tandem: MS/MS, MSn. 3.2.- Detectors: Faraday Cup, Multichannel plate… |
| 4.- Hyphenated Methods: GC-MS, LC-MS |
|
| MAGNETIC NUCLEAR RESONANCE |
|
| 5. Presentation. Aims. Bibliography. | |
| 6. Theoretical basis of NMR. The nucleus in a magnetic field. Vector model. Pulses. Relaxation. | |
| 7. Pulse Experiments. Spectra in the time domain and frequency domain. Operators. |
|
| 8. Instrumental aspects. Acquisition and processing of spectra. |
|
| 9. Spectral parameters in NMR: Magnetic symmetry and equivalence. Second order effects. Simulation programmes. Exchange processes and dynamical systems. |
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| 10. Spectral modifications: Shift reagents. Spin uncoupling. Nuclear Overhauser effect. |
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| 11. Multiple pulse experiments. |
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| 12. Bidimensional resonance experiments. |
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| 13. Other experiments in NMR. |
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| 14. Practical cases and problem solving. |
